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TRI-ALLATE ICSC: 0201
Date of Peer Review: April 2005

S-(2,3,3-Trichloroallyl) diisopropylthiocarbamate
S-(2,3,3-Trichloro-2-propenyl) bis(1-methylethyl)carbamothioate
CAS # 2303-17-5 C10H16Cl3NOS / ((CH3)2CH)2NCOSCH2CCl=CCl2
RTECS # EZ8575000 Molecular mass: 304.7
UN #
EC Index # 006-039-00-X
TYPES OF HAZARD / EXPOSURE ACUTE HAZARDS / SYMPTOMS PREVENTION FIRST AID / FIRE FIGHTING
FIRE Combustible. Liquid formulations containing organic solvents may be flammable. Gives off irritating or toxic fumes (or gases) in a fire.
NO open flames.
In case of fire in the surroundings: use appropriate extinguishing media.
EXPLOSION


EXPOSURE


Inhalation
Avoid inhalation of fine dust and mist.
Fresh air, rest.
Skin Redness.
Protective gloves.
Remove contaminated clothes. Rinse skin with plenty of water or shower.
Eyes Redness.
Safety spectacles.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
Ingestion
Do not eat, drink, or smoke during work. Wash hands before eating.
Rinse mouth. Refer for medical attention.
SPILLAGE DISPOSAL PACKAGING & LABELLING
Personal protection: A/P2 filter respirator for organic vapour and harmful dust. Collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent and remove to safe place. Do NOT let this chemical enter the environment.
Do not transport with food and feedstuffs.
EU Classification
Symbol: Xn, N
R: 22-43-48/22-50/53
S: (2-)-24-37-60-61
UN Classification

EMERGENCY RESPONSE STORAGE

Store in an area without drain or sewer access. Separated from food and feedstuffs.
IPCS
International
Programme on
Chemical Safety
Prepared in the context of cooperation between the International Programme on Chemical Safety and the Commission of the European Communities IPCS, CEC 2005

SEE IMPORTANT INFORMATION ON BACK
TRI-ALLATE ICSC: 0201
IMPORTANT DATA
PHYSICAL STATE; APPEARANCE:
CLEAR LIQUID OR COLOURLESS CRYSTALS

CHEMICAL DANGERS:
The substance decomposes on heating above 200C producing toxic and corrosive gases including hydrogen chloride nitrogen oxides and sulfur oxides. Attacks many metals.

OCCUPATIONAL EXPOSURE LIMITS:
TLV not established.
MAK not established.
ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation and by ingestion.

INHALATION RISK:
A harmful concentration of airborne particles can be reached quickly on spraying or when dispersed, especially if powdered.

EFFECTS OF SHORT-TERM EXPOSURE:
The substance is irritating to the eyes and the skin.

PHYSICAL PROPERTIES
Boiling point at 0.04 kPa: 117C
Melting point: 29-30C
Relative density (water = 1): 1.27
Solubility in water, g/100 ml at 25C: 0.0002
Vapour pressure, Pa at 25C: 0.016
Relative vapour density (air = 1): 10.5
Flash point: 90C c.c.
Octanol/water partition coefficient as log Pow: 3.98 (calculated)
ENVIRONMENTAL DATA
The substance is very toxic to aquatic organisms. Bioaccumulation of this chemical may occur in aquatic organisms. This substance does enter the environment under normal use. Great care, however, should be given to avoid any additional release, e.g. through inappropriate disposal.
NOTES
Technical Tri-allate is an oily amber liquid. If the substance is formulated with solvents also consult the ICSCs of these materials. Carrier solvents used in commercial formulations may change physical and toxicological properties. Avadex BW, Dipthal and Far-Go are trade names.
ADDITIONAL INFORMATION


LEGAL NOTICE Neither the CEC nor the IPCS nor any person acting on behalf of the CEC or the IPCS is responsible for the use which might be made of this information
IPCS, CEC 2005