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1-HEXANOL ICSC: 1084
Date of Peer Review: October 2002

Hexyl alcohol
n-Hexanol
n-Hexyl alcohol
1-Hydroxyhexane
Amyl carbinol
Caproyl alcohol
CAS # 111-27-3 C6H14O / CH3(CH2)4CH2OH
RTECS # MQ4025000 Molecular mass: 102.2
UN #
EC # 603-059-00-6
TYPES OF HAZARD / EXPOSURE ACUTE HAZARDS / SYMPTOMS PREVENTION FIRST AID / FIRE FIGHTING
FIRE Combustible.
NO open flames.
Alcohol-resistant foam, dry powder, carbon dioxide.
EXPLOSION Above 63C explosive vapour/air mixtures may be formed.
Above 63C use a closed system, ventilation.
In case of fire: keep drums, etc., cool by spraying with water.
EXPOSURE


Inhalation Cough. Sore throat.
Ventilation, local exhaust, or breathing protection.
Fresh air, rest.
Skin Dry skin.
Protective gloves.
Rinse and then wash skin with water and soap.
Eyes Redness. Pain.
Safety goggles.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
Ingestion Burning sensation.
Do not eat, drink, or smoke during work.
Rinse mouth. Do NOT induce vomiting. Give plenty of water to drink.
SPILLAGE DISPOSAL PACKAGING & LABELLING
Collect leaking liquid in covered containers. Absorb remaining liquid in sand or inert absorbent and remove to safe place. (Extra personal protection: filter respirator for organic gases and vapours.)
EU Classification
Symbol: Xn
R: 22
S: (2-)-24/25
UN Classification

EMERGENCY RESPONSE STORAGE
NFPA Code: H1; F2; R0;
Separated from strong oxidants.
IPCS
International
Programme on
Chemical Safety
Prepared in the context of cooperation between the International Programme on Chemical Safety and the Commission of the European Communities IPCS, CEC 1999

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1-HEXANOL ICSC: 1084
IMPORTANT DATA
PHYSICAL STATE; APPEARANCE:
COLOURLESS LIQUID, WITH CHARACTERISTIC ODOUR.

CHEMICAL DANGERS:
Reacts with strong oxidants.

OCCUPATIONAL EXPOSURE LIMITS:
TLV not established.
ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation and by ingestion.

INHALATION RISK:
No indication can be given about the rate in which a harmful concentration in the air is reached on evaporation of this substance at 20C.

EFFECTS OF SHORT-TERM EXPOSURE:
The substance is irritating to the respiratory tract and the skin. The substance is severely irritating to the eyes. If this liquid is swallowed, aspiration into the lungs may result in chemical pneumonitis.

EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
The liquid defats the skin.
PHYSICAL PROPERTIES
Boiling point: 157C
Melting point: -44.6C
Relative density (water = 1): 0.82
Solubility in water, g/100 ml at 20C: 0.59
Vapour pressure, kPa at 25C: 0.124
Relative vapour density (air = 1): 3.52
Relative density of the vapour/air-mixture at 20C (air = 1): 1
Flash point: 63C c.c.
Auto-ignition temperature: 290C
Explosive limits, vol% in air: 1.2-7.7 calculated
Octanol/water partition coefficient as log Pow: 2.03
ENVIRONMENTAL DATA

NOTES

ADDITIONAL INFORMATION


LEGAL NOTICE Neither the CEC nor the IPCS nor any person acting on behalf of the CEC or the IPCS is responsible for the use which might be made of this information
IPCS, CEC 1999
See Also:
        n-Hexanol (CHEMINFO)